Isotopomeric conformational change in anisole-water

被引：53

作者：

Giuliano, BM ^{[1
]}

Caminati, W ^{[1
]}

机构：

[1] Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 04期

关键词：

D O I：

10.1002/anie.200461860

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The deuteration of water produces the conformational change shown in the figure in the anisole⋯water complex. The value of the θ angle decreases from 138 to 128°, and the secondary interaction O⋯H Me is replaced by O⋯HPh.

引用

页码：603 / 606

页数：4

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