The viscosity and density of n-dodecane and n-octadecane at pressures up to 200 MPa and temperatures up to 473 K

被引:185
作者
Caudwell, DR
Trusler, JPM
Vesovic, V
Wakeham, WA
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, London SW7 2AZ, England
[2] Univ London Imperial Coll Sci Technol & Med, Dept Earth Sci & Engn, London SW7 2AZ, England
[3] Univ Southampton, Southampton SO17 1BJ, Hants, England
基金
英国工程与自然科学研究理事会;
关键词
density; dodecane; high pressure; high temperature; octadecane; viscosity;
D O I
10.1007/s10765-004-5742-0
中图分类号
O414.1 [热力学];
学科分类号
摘要
A vibrating-wire instrument for simultaneous measurement of the density and viscosity of liquids under conditions of high pressure is described. The instrument is capable of operation at temperatures between 298.15 and 473.15 K at pressures up to 200 MPa. Calibration was performed by means of measurements in vacuum, air, and toluene at 298.15 K. For n-dodecane measurements were made along eight isotherms between 298.15 and 473.15 at pressures up to 200 Pa, while for n-octadecane measurements were measured along seven isotherms between 323.15 and 473.15 at pressures up to 90 Pa. The estimated uncertainty of the results is 2% in viscosity and 0.2% in density. Comparisons with literature data are presented.
引用
收藏
页码:1339 / 1352
页数:14
相关论文
共 27 条
[1]  
*AM SOC MET HDB CO, 1979, MET HDB NONF ALL PUR
[2]   Reference correlation for the viscosity of liquid toluene from 213 to 373 K at pressures to 250 MPa [J].
Assael, MJ ;
Avelino, HMT ;
Dalaouti, NK ;
Fareleira, JMNA ;
Harris, KR .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2001, 22 (03) :789-799
[3]   VIBRATING-WIRE VISCOMETERS FOR LIQUIDS AT HIGH-PRESSURES [J].
ASSAEL, MJ ;
OLIVEIRA, CP ;
PAPADAKI, M ;
WAKEHAM, WA .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1992, 13 (04) :593-615
[4]   Simultaneous measurement of density and viscosity of n-pentane from 298 to 383 K and up to 100 MPa using a vibrating-wire instrument [J].
Audonnet, F ;
Pádua, AAH .
FLUID PHASE EQUILIBRIA, 2001, 181 (1-2) :147-161
[5]  
da Mata JLGC, 2001, HIGH TEMP-HIGH PRESS, V33, P669, DOI 10.1068/htwu275
[6]   A VIBRATING-WIRE DENSIMETER FOR MEASUREMENTS IN FLUIDS AT HIGH-PRESSURES [J].
DIX, M ;
FARELEIRA, JMNA ;
TAKAISHI, Y ;
WAKEHAM, WA .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1991, 12 (02) :357-370
[7]  
DUCOULOMBIER D, 1986, J PHYS CHEM-US, V90, P1692, DOI 10.1021/j100399a047
[8]   Pressure and temperature dependence of the speed of sound and related properties in normal octadecane and nonadecane [J].
Dutour, S ;
Daridon, JL ;
Lagourette, B .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2000, 21 (01) :173-184
[9]  
Dymond J. H., 1981, Int.J. Thermophys, V2, P133, DOI DOI 10.1007/BF00503937
[10]   THE VISCOSITY OF LIQUID TOLUENE AT ELEVATED PRESSURES [J].
DYMOND, JH ;
GLEN, NF ;
ISDALE, JD ;
PYDA, M .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1995, 16 (04) :877-882