Highly reduced organometallics -: 42.: A new method for the syntheses of [V(CO)6]- and [V(PF3)6]- involving anthracenide mediated reductions of VCl3(THF)3

被引：18

作者：

Barybin, MV ^{[1
]}

Pomije, MK ^{[1
]}

Ellis, JE ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

INORGANICA CHIMICA ACTA | 1998年 / 269卷 / 01期

基金：

美国国家科学基金会;

关键词：

vanadium complexes; carbonyl complexes; trifluorophosphine complexes; anion complexes;

D O I：

10.1016/S0020-1693(97)05771-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mild (0 degrees C, 1 atm P) and high yield (70%) synthesis of [V(CO)(6)](-) by the sodium anthracenide mediated reductive carbonylation of VCl3(THF)(3) is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF3)(6)](-), a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates. (C) 1998 Elsevier Science S.A.

引用

页码：58 / 62

页数：5

共 36 条

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