Highly reduced organometallics -: 42.: A new method for the syntheses of [V(CO)6]- and [V(PF3)6]- involving anthracenide mediated reductions of VCl3(THF)3

被引:18
作者
Barybin, MV [1 ]
Pomije, MK [1 ]
Ellis, JE [1 ]
机构
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
基金
美国国家科学基金会;
关键词
vanadium complexes; carbonyl complexes; trifluorophosphine complexes; anion complexes;
D O I
10.1016/S0020-1693(97)05771-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new mild (0 degrees C, 1 atm P) and high yield (70%) synthesis of [V(CO)(6)](-) by the sodium anthracenide mediated reductive carbonylation of VCl3(THF)(3) is presented. This same procedure is also shown to provide the first conventional, non-photolytic route to [V(PF3)(6)](-), a remarkably stable substance. Corresponding sodium naphthalenide reductions provide much lower yields of these vanadates. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:58 / 62
页数:5
相关论文
共 36 条