Photocatalytic reductive dechlorination of chlorobenzene to benzene in 2-propanol suspension of metal-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide

被引：49

作者：

Fuku, Kojirou ^{[1
]}

Hashimoto, Keiji ^{[1
]}

Kominami, Hiroshi ^{[1
]}

机构：

[1] Kinki Univ, Dept Appl Chem, Fac Sci & Engn, Osaka 5778502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 28期

关键词：

CATALYST; DEHALOGENATION; DERIVATIVES;

D O I：

10.1039/c0cc00589d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photocatalytic reaction of chlorobenzene in 2-propanol suspension of palladium- and rhodium-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide under deaerated conditions, in which 2-propanol, metal loaded (palladium and rhodium) and sodium hydroxide effectively acted as hole scavenger, co-catalyst and chloride solidifier, respectively, quantitatively gave benzene and chloride ions with a high stoichiometry.

引用

页码：5118 / 5120

页数：3

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