The H(H)over-bar1Σg state of the hydrogen molecule

被引：35

作者：

Wolniewicz, L ^{[1
]}

机构：

[1] Nicholas Copernicus Univ, Inst Phys, PL-87100 Torun, Poland

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 108卷 / 04期

关键词：

D O I：

10.1063/1.475521

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Born-Oppenheimer potential and adiabatic corrections for the H (H) over bar(1) Sigma(g)(+), state of the hydrogen molecule are given for internuclear distances up to 80 a.u. Term values in the outer well are computed for J less than or equal to 5. A comparison with experiment shows that the theoretical total energies are too low by about 1 cm(-1). The source of this discrepancy is briefly discussed. (C) 1998 American Institute of Physics. [S0021-9606(98)02004-2].

引用

页码：1499 / 1502

页数：4

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