Magnesium secondary alloys: Alloy design for magnesium alloys with improved tolerance limits against impurities

被引:76
作者
Blawert, C. [1 ]
Fechner, D. [1 ]
Hoeche, D. [1 ]
Heitmann, V. [1 ]
Dietzel, W. [1 ]
Kainer, K. U. [1 ]
Zivanovic, P. [2 ]
Scharf, C. [2 ]
Ditze, A. [2 ]
Groebner, J. [2 ]
Schmid-Fetzer, R. [2 ]
机构
[1] GKSS Forschungszentrum Geesthacht GmbH, D-21502 Geesthacht, Germany
[2] Tech Univ Clausthal, Inst Met, D-38678 Clausthal Zellerfeld, Germany
关键词
Magnesium; Secondary alloy; Intermetallics; Weight loss; Hydrogen over-potential; CORROSION BEHAVIOR; MECHANICAL-PROPERTIES; MICROSTRUCTURE; AZ63; CONSTITUENT;
D O I
10.1016/j.corsci.2010.03.035
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
The development of secondary magnesium alloys requires a completely different concept compared with standard alloys which obtain their corrosion resistance by reducing the levels of impurities below certain alloy and process depending limits. The present approach suitable for Mg-Al based cast and wrought alloys uses a new concept replacing the beta-phase by tau-phase, which is able to incorporate more impurities while being electro-chemically less detrimental to the matrix. The overall experimental effort correlating composition, microstructure and corrosion resistance was reduced by using thermodynamic calculations to optimise the alloy composition. The outcome is a new, more impurity tolerant alloy class with a composition between the standard AZ and ZC systems having sufficient ductility and corrosion properties comparable to the high purity standard alloys. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2452 / 2468
页数:17
相关论文
共 45 条
[1]
Studies on the influence of chloride ion concentration and pH on the corrosion and electrochemical behaviour of AZ63 magnesium alloy [J].
Altun, H ;
Sen, S .
MATERIALS & DESIGN, 2004, 25 (07) :637-643
[2]
Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy [J].
Ambat, R ;
Aung, NN ;
Zhou, W .
CORROSION SCIENCE, 2000, 42 (08) :1433-1455
[3]
Volta potential of second phase particles in extruded AZ80 magnesium alloy [J].
Andreatta, F ;
Apachitei, I ;
Kodentsov, AA ;
Dzwonczyk, J ;
Duszczyk, J .
ELECTROCHIMICA ACTA, 2006, 51 (17) :3551-3557
[4]
Corrosion characteristics of Alloy AZ63 in buffered neutral solutions [J].
Anik, Mustafa ;
Gunesdogdu, Ilter M. .
MATERIALS & DESIGN, 2010, 31 (06) :3100-3105
[5]
[Anonymous], MAGNESIUM
[6]
[Anonymous], [No title captured]
[7]
Beck A., 1939, MAGNESIUM SEINE LEGI
[8]
The relation between microstructure and corrosion behavior of GTA welded AZ31B magnesium sheet [J].
Ben-Hamu, G. ;
Eliezer, D. ;
Cross, C. E. ;
Boellinghaus, Th. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2007, 452 :210-218
[9]
CRYSTAL STRUCTURE OF THE INTERMETALLIC COMPOUND MG32(AL,ZN)49 AND RELATED PHASES [J].
BERGMAN, G ;
WAUGH, JLT ;
PAULING, L .
NATURE, 1952, 169 (4312) :1057-1058
[10]
Bharadwaj MD, 2008, MAGNESIUM TECHNOLOGY, P389