The capacity deterioration model of mechanically alloyed MgXNi100-X amorphous electrodes in charging-discharging cycling

被引：15

作者：

Liu, WH ^{[1
]}

Lei, YQ ^{[1
]}

Wu, J ^{[1
]}

Wang, QD ^{[1
]}

机构：

[1] ZHEJIANG UNIV,DEPT MAT SCI & ENGN,HANGZHOU 310027,PEOPLES R CHINA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 1997年 / 22卷 / 10-11期

关键词：

D O I：

10.1016/S0360-3199(96)00022-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, a relationship between the electrochemical capacity of mechanically alloyed MgXNi100-X amorphous hydride electrodes and discharging time is deduced on the basis of oxidation of Mg and Ni. The experimental data are in good agreement with the deduced relation. Analysis shown that this is the common mechanism of hydride electrode degradation when the activation process is ignored. The parameters m and B of some amorphous hydrides art calculated on the basis of this relation. (C) 1997 International Association for Hydrogen Energy.

引用

页码：999 / 1003

页数：5

共 15 条

[1] Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184

[2] Kinetics of phase change I - General theory [J].

Avrami, M .

JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112

[3]

Avrami M., 1940, J CHEM PHYS, V8, P212, DOI [10.1063/1.1750631, DOI 10.1063/1.1750631]

[4]

EROFEYEV BV, 1946, CR DOKL ACAD SCI URS, V52, P511

[5] METHOD OF COMPARING SOLID-STATE KINETIC DATA AND ITS APPLICATION TO DECOMPOSITION OF KAOLINITE, BRUCITE, AND BACO3 [J].

HANCOCK, JD ;

SHARP, JH .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1972, 55 (02) :74-&

[6]

Hulbert S. F, 1969, J BRIT CERAM SOC, V6, P11

[7]

Johnson WA, 1939, T AM I MIN MET ENG, V135, P416

[8]

LEI YQ, 1994, Z PHYS CHEM

[9]

LI ZP, 1992, INT S MET HYDR SYST

[10]

LI ZP, 1994, Z PHYS CHEM BD, V183, pS287

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