Ionogels encompassing ionic liquid with liquid like performance preferable for fast solid state electrochromic devices

被引：36

作者：

Ahmad, Shahzada ^{[1
]}

Deepa, M. ^{[1
]}

机构：

[1] Natl Phys Lab, Elect Mat Div, New Delhi 1100112, India

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2007年 / 9卷 / 07期

关键词：

ionic liquids; sol-gel; electrochromic devices; electrolytes; fast kinetics ECD;

D O I：

10.1016/j.elecom.2007.02.022

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Novel ionogels encompassing an ionic liquid encaged in an inorganic matrix were synthesized by sol-gel chemistry. The ability of these highly conducting ionogels (similar to 10(-2) S cm(-1) at 25 degrees C) to act as liquid electrolytes in spite of their solid form has been exploited in inorganic electrochromic devices based on tungsten oxide and Prussian blue electrodes. These devices exhibit extremely fast switching kinetics and make it the best and only candidate for the realization of fast all solid state electrochromic devices. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：1635 / 1638

页数：4

共 20 条

[1] Electrodeposited Prussian blue films: Annealing effect [J].

Agnihotry, S. A. ;

Singh, Punita ;

Joshi, Amish G. ;

Singh, D. P. ;

Sood, K. N. ;

Shivaprasad, S. M. .

ELECTROCHIMICA ACTA, 2006, 51 (20) :4291-4301

[2] Smart Electrochromic Windows (SECWs) for energy management [J].

Agnihotry, SA ;

Saxena, TK ;

Deepa, M ;

Verma, A ;

Ahmad, S ;

Ahmad, S .

IONICS, 2004, 10 (3-4) :226-232

[3]

AGRAWAL A, 2004, Patent No. 0257633

[4]

Ahmad S, 2006, E-POLYMERS

[5]

Deb S K, 1969, Appl Opt, V8 Suppl 1, P192

[6] Influence of annealing on electrochromic performance of template assisted, electrochemically grown, nanostructured assembly of tungsten oxide [J].

Deepa, M. ;

Srivastava, A. K. ;

Agnihotry, S. A. .

ACTA MATERIALIA, 2006, 54 (17) :4583-4595

[7] Electrochromic nanostructured tungsten oxide films by sol-gel: Structure and intercalation properties [J].

Deepa, M ;

Joshi, AG ;

Srivastava, AK ;

Shivaprasad, SM ;

Agnihotry, SA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (05) :C365-C376

[8] Electrochromic coatings and devices:: survey of some recent advances [J].

Granqvist, CG ;

Avendaño, E ;

Azens, A .

THIN SOLID FILMS, 2003, 442 (1-2) :201-211

[9] Ion gels by self-assembly of a triblock copolymer in an ionic liquid [J].

He, Yiyong ;

Boswell, Paul G. ;

Buhlmann, Philippe ;

Lodge, Timothy P. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (18) :4645-4652

[10] Performance of an electrochromic window based on polyaniline, prussian blue and tungsten oxide [J].

Jelle, BP ;

Hagen, G .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1999, 58 (03) :277-286

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