Towards nanostructured arrays of single molecule magnets: : new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis

被引：197

作者：

Goodwin, JC

Sessoli, R

Gatteschi, D

Wernsdorfer, W

Powell, AK

Heath, SL

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[3] Univ Florence, Dipartimento Chim, I-50144 Florence, Italy

[4] CNRS, Lab Louis Neel, F-38042 Grenoble 9, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 12期

关键词：

D O I：

10.1039/b002135k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ligands of general formula N(CHRCH2OH)(CH2CO2H)(2) have been used to capture portions of the Fe(OH)(2)(+) lattice to give particles containing up to nineteen magnetically coupled iron(III) centres. If R = Me or Et, lattices containing only Fe-19 clusters result and single crystal X-ray diffraction shows that these are arranged in tilted stacks. These clusters act as single molecule magnets, pointing the way forward to engineering ordered arrays of magnetic particles. The packing of such materials is independent of the counter anion, NO3- or Cl-, used.

引用

页码：1835 / 1840

页数：6

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