Size effect in morphotropic phase boundary Pb(Mg1/3Nb2/3)O3-PbTiO3

被引:62
作者
Alguero, M.
Ricote, J.
Jimenez, R.
Ramos, P.
Carreaud, J.
Dkhil, B.
Kiat, J. M.
Holc, J.
Kosec, M.
机构
[1] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain
[2] Univ Alcala de Henares, Dept Elect, E-28871 Madrid, Spain
[3] Ecole Cent Paris, CNRS, UMR 8580, Lab Struct Proprietes & Modelisat Solides, F-92295 Chatenay Malabry, France
[4] CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France
[5] Jozef Stefan Inst, SL-1000 Ljubljana, Slovenia
关键词
D O I
10.1063/1.2778471
中图分类号
O59 [应用物理学];
学科分类号
摘要
Phases, domain configuration, and properties of 0.65Pb(Mg1/3Nb2/3)O-3-0.35PbTiO(3) ceramics with grain sizes of 4 and 0.15 mu m have been studied. The average phase is monoclinic Pm in coexistence with tetragonal. An evolution from micron-sized lamellar domains towards submicron/nanometer sized crosshatched domains is found with the decrease in size, which results in electrical relaxor type behavior and hindered switching. This is proposed to be associated with the slowing down of the relaxor to ferroelectric transition that causes the long time presence of an intermediate domain configuration. Nevertheless, a high sensitivity piezoelectric submicron-structured material is obtained under tailored poling (d(33)similar to 300 pC N-1).
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页数:3
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