Photosensitized NO release from water-soluble nanoparticle assemblies

被引：61

作者：

Neuman, Daniel

Ostrowski, Alexis D.

Absalonson, Ryan O.

Strouse, Geoffrey F.

Ford, Peter C. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[2] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 14期

关键词：

D O I：

10.1021/ja070490w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoluminescence from CdSe/ZnS core/shell quantum dots, modified to make them water-soluble by exchanging the surface ligands with dihydrolipoic acid, is partially quenched by adding the chromium(III) complex trans-Cr(cylcam)(ONO)(2)(+) (1, BF4- salt). This quenching, attributed to the formation of electrostatic assemblies due to ion pairing of 1 with the negatively charged QD surface, is accompanied by the release of NO owing to photosensitized reaction of the Cr(III) nitrito complex.

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页码：4146 / +

页数：3

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