Estimating measurement uncertainty: reconciliation using a cause and effect approach

被引:46
作者
Ellison, SLR [1 ]
Barwick, VJ [1 ]
机构
[1] Lab Govt Chemist, Teddington TW11 0LY, Middx, England
关键词
measurement uncertainty; validation; reconciliation; cause and effect analysis;
D O I
10.1007/s007690050198
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A strategy is presented for applying existing data and planning necessary additional experiments for uncertainty estimation. The strategy has two stages: identifying and structuring the input effects, followed by an explicit reconciliation stage to assess the degree to which information available meets the requirement and thus identify factors requiring further Study. A graphical approach to identifying and structuring the in put effects on a measurement result is presented. The methodology promotes consistent identification of important effects, and permits effective application of prior data with minimal risk of duplication or omission. The results of applying the methodology are discussed, with particular reference to the use of planned recovery and precision studies.
引用
收藏
页码:101 / 105
页数:5
相关论文
共 9 条
[1]  
[Anonymous], 1989, J ASSOC OFF ANA CHEM, V72, P694
[2]  
[Anonymous], 1995, ANALYST, V120, P2303
[3]  
ELLISON SLR, IN PRESS ACCRED QUAL
[4]  
ELLISON SLR, 1997, ADV MATH TOOLS METRO, V3, P56
[5]  
*EURACHEM, 1995, GUID QUANT UNC AN ME
[6]   PROTOCOL FOR THE DESIGN, CONDUCT AND INTERPRETATION OF COLLABORATIVE STUDIES [J].
HORWITZ, W .
PURE AND APPLIED CHEMISTRY, 1988, 60 (06) :855-864
[7]  
International Organization for Standardization, 1993, GUID EXPR UNC MEAS
[8]  
*ISO, 1993, 90044 ISO 2
[9]  
*ISO, 1995, 5725 ISO