Template-directed synthesis of a π-conjugated porphyrin nanoring

被引:165
作者
Hoffmann, Markus [1 ]
Wilson, Craig J. [1 ]
Odell, Barbara [1 ]
Anderson, Harry L. [1 ]
机构
[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England
关键词
molecular wires; nanostructures; porphyrinoids; self-assembly; template synthesis;
D O I
10.1002/anie.200604601
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Round the bend: Bending a molecular wire round an eight-spoked template leads to the formation of a highly symmetric belt-shaped it system (green in picture). Addition of a large excess of pyridine releases the corresponding cyclic octamer from the template. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3122 / 3125
页数:4
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