Quasi-chemical phase diagrams for orienting mixtures

被引:8
作者
Hueda, Y
Costas, ME
Scott, RL
机构
[1] UNIV NACL AUTONOMA MEXICO, FAC QUIM, MEXICO CITY 04510, DF, MEXICO
[2] UNIV CALIF LOS ANGELES, DEPT CHEM & BIOCHEM, LOS ANGELES, CA 90095 USA
关键词
D O I
10.1021/jp971131y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Phase diagrams of quasi-lattice mixtures with orienting forces are calculated using the quasi-chemical approximation. Two different coordination numbers and three different cases of the interaction parameters between faces of molecules are studied. In some, closed loops are observed, while in others extra features like several different three-phase regions, triple points, double critical points, and a special point, a critical double point, are found.
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页码:8676 / 8682
页数:7
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