The AlphOx™ process or the one-step hydroxylation of benzene into phenol by nitrous oxide. Understanding and tuning the ZSM-5 catalyst activities

被引：93

作者：

Notté, PP ^{[1
]}

机构：

[1] Solutia Inc, Pensacola Plant & Tech Ctr, Gonzalez, FL 32560 USA

来源：

TOPICS IN CATALYSIS | 2000年 / 13卷 / 04期

关键词：

AlphOx; phenol; nitrous oxide; ZSM-5; zeolite; alpha-site; alpha-oxygen; Bronsted acidity; benzene; one-step conversion of benzene to phenol;

D O I：

10.1023/A:1009015223793

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The required activities for the ZSM-5 in the AlphOx(TM), one-step conversion of benzene into phenol with nitrous oxide, are investigated. It is shown that both Bronsted acidity and the alpha-sites, linked to the presence of iron, are necessary. Previous reports on the subject are discussed.

引用

页码：387 / 394

页数：8

共 32 条

[1] 2-PROPANAMINE ADSORPTION ON A FLUID CATALYTIC CRACKING CATALYST [J].

BIAGLOW, AI ;

GITTLEMAN, C ;

GORTE, RJ ;

MADON, RJ .

JOURNAL OF CATALYSIS, 1991, 129 (01) :88-93

[2] MAGIC-ANGLE-SPINNING NMR-STUDIES OF ACID SITES IN ZEOLITE H-ZSM-5 [J].

BRUNNER, E ;

ERNST, H ;

FREUDE, D ;

FROHLICH, T ;

HUNGER, M ;

PFEIFER, H .

JOURNAL OF CATALYSIS, 1991, 127 (01) :34-41

[3] INVESTIGATION OF ZEOLITE CATALYSTS FOR THE DIRECT PARTIAL OXIDATION OF BENZENE TO PHENOL [J].

BURCH, R ;

HOWITT, C .

APPLIED CATALYSIS A-GENERAL, 1993, 103 (01) :135-162

[4]

BURCH R, 1992, APPL CATAL, V86, P135

[5]

CHU P, 1983, ACS SYM SER, V218, P59

[6]

CORMA A, 1993, P 9 INT ZEOL C MONTR, P379

[7] NON-EMPIRICAL QUANTUM CHEMICAL STUDY OF THE SITING AND PAIRING OF ALUMINUM IN THE MFI FRAMEWORK [J].

DEROUANE, EG ;

FRIPIAT, JG .

ZEOLITES, 1985, 5 (03) :165-172

[8] What do we know about the acidity of solid acids? [J].

Gorte, RJ .

CATALYSIS LETTERS, 1999, 62 (01) :1-13

[9]

GUBELMANN H, Patent No. 5001280

[10]

GUBELMANN M, Patent No. 0341113

← 1 2 3 4 →