In this paper, we have investigated the performance and reliability of dual-gate (N+-poly for NMOS and p(+)-poly for PMOS) CMOS devices with gate oxides grown on Nitrogen Implanted Si Substrates (NISS). Oxynitride gate dielectrics (28 similar to 63 Angstrom) were fabricated with several nitrogen implantation doses and compared with control SiO2 of identical thicknesses. Our results indicate that as gate oxide thickness is scaled down, NISS oxides show improvements over control SiO2 in maximum transconductance, subthreshold swing, as well as on- and off-state drain current for both N- and PMOSFETs. Hot-carrier stressing is performed on both NISS and control devices of identical gate oxide thickness (36 Angstrom). Compared to control SiO2, NISS oxide devices show longer device lifetime and suppressed gate-induced drain leakage (GIDL) current for PMOSFETs under I-g,I-max stressing. No difference in NMOSFET degradation (Delta V-t, Delta G(m)) is observed under I-sub,I-max stressing. However, significant degradation under hot hole injection (V-g=V-d) compared to control SiO2 is observed in NISS P+-poly PMOSFETs. In addition, degradation of NISS oxide TDDB is observed.