Practical heterogeneous catalysts for epoxide production

被引:141
作者
De Vos, DE [1 ]
Sels, BF [1 ]
Jacobs, PA [1 ]
机构
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium
关键词
alkenes; allylic alcohols; epoxidation; heterogeneous catalysis; manganese; peroxides; titanium; tungsten;
D O I
10.1002/adsc.200390051
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
An overview of heterogeneous epoxidation catalysts is given, with an emphasis on practical parameters such as catalyst productivity, turnover numbers and stereoselectivity. Special focus is directed towards catalysts that have resulted from research in the authors' group.
引用
收藏
页码:457 / 473
页数:17
相关论文
共 124 条
[1]   Diastereoselective epoxidation of allylic alcohols with hydrogen peroxide catalyzed by titanium-containing zeolites or methyltrioxorhenium versus stoichiometric oxidation with dimethyldioxirane: Clues on the active species in the zeolite lattice [J].
Adam, W ;
Corma, A ;
Martinez, A ;
Mitchell, CM ;
Reddy, TI ;
Renz, M ;
Smerz, AK .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 117 (1-3) :357-366
[2]   Titanium-catalyzed heterogeneous oxidations of silanes, chiral allylic alcohols, 3-alkylcyclohexanes, and thianthrene 5-oxide:: A comparison of the reactivities and selectivities for the large-pore zeolite Ti-β, the mesoporous Ti-MCM-41, and the layered alumosilicate Ti-ITQ-2 [J].
Adam, W ;
Corma, A ;
García, H ;
Weichold, O .
JOURNAL OF CATALYSIS, 2000, 196 (02) :339-344
[3]   Diastereoselective catalytic epoxidation of chiral allylic alcohols by the TS-1 and Ti-beta zeolites: Evidence for a hydrogen-bonded, peroxy-type loaded complex as oxidizing species [J].
Adam, W ;
Corma, A ;
Reddy, TI ;
Renz, M .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (11) :3631-3637
[4]   Chemo- and diastereoselective epoxidation of chiral allylic alcohols with the urea hydrogen peroxide adduct, catalyzed by titanium silicate 1 [J].
Adam, W ;
Kumar, R ;
Reddy, TI ;
Renz, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (08) :880-882
[5]  
[Anonymous], 2001, FINE CHEM HETEROGENE
[6]  
[Anonymous], ANGEW CHEM
[7]   REACTIONS OF TITANIUM SILICALITE WITH PROTIC MOLECULES AND HYDROGEN-PEROXIDE [J].
BELLUSSI, G ;
CARATI, A ;
CLERICI, MG ;
MADDINELLI, G ;
MILLINI, R .
JOURNAL OF CATALYSIS, 1992, 133 (01) :220-230
[8]   Intramolecular rearrangement of epoxides generated in situ over titanium silicate molecular sieves [J].
Bhaumik, A ;
Tatsumi, T .
JOURNAL OF CATALYSIS, 1999, 182 (02) :349-356
[9]   Selective dihydroxylation over titanium silicate molecular sieves [J].
Bhaumik, A ;
Tatsumi, T .
JOURNAL OF CATALYSIS, 1998, 176 (02) :305-309
[10]   Organically modified titanium-rich Ti-MCM-41, efficient catalysts for epoxidation reactions [J].
Bhaumik, A ;
Tatsumi, T .
JOURNAL OF CATALYSIS, 2000, 189 (01) :31-39