Characterization of ordered mesoporous films on silicon (001) surface using X-ray and electron diffraction

被引:6
作者
Liu, PH
Chao, KJ [1 ]
Guo, XJ
Huang, KY
Lee, YR
Cheng, CW
Chiu, MS
Chang, SL
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan
[2] Natl Tsing Hua Univ, Dept Phys, Hsinchu 300, Taiwan
关键词
D O I
10.1107/S0021889804031498
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A continuous silica film with well aligned mesochannels parallel to the Si( 001) surface was found to be formed through sol - gel dip-coating of a silica precursor with nonionic ethylene oxide surfactant. Two two-dimensional mesoporous structures in centered and non-centered rectangular symmetries and with the short axes of elongated ellipsoidal pores normal to the surface were observed by X-ray and electron diffraction. Detailed transmission electron microscopy investigations were employed to view the direction dependence of the channel or pore packing in the continuous film.
引用
收藏
页码:211 / 216
页数:6
相关论文
共 18 条
[1]  
Baskaran S, 2000, ADV MATER, V12, P291, DOI 10.1002/(SICI)1521-4095(200002)12:4<291::AID-ADMA291>3.0.CO
[2]  
2-P
[3]  
Bruinsma P. J., 1999, Patent No. [US5922299(A), 5922299]
[4]   Microstructure and mechanical properties of surfactant templated nanoporous silica thin films: Effect of methylsilylation [J].
Chen, JY ;
Pan, FM ;
Cho, AT ;
Chao, KJ ;
Tsai, TG ;
Wu, BW ;
Yang, CM ;
Chang, L .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) :F123-F127
[5]  
Dag Ö, 1999, ADV MATER, V11, P474, DOI 10.1002/(SICI)1521-4095(199904)11:6<474::AID-ADMA474>3.0.CO
[6]  
2-I
[7]   Rapid prototyping of patterned functional nanostructures [J].
Fan, HY ;
Lu, YF ;
Stump, A ;
Reed, ST ;
Baer, T ;
Schunk, R ;
Perez-Luna, V ;
López, GP ;
Brinker, CJ .
NATURE, 2000, 405 (6782) :56-60
[8]  
Ho P. S., 2003, LOW DIELECTRIC CONST
[9]   SYNTHESIS OF HIGHLY ORDERED MESOPOROUS MATERIALS FROM A LAYERED POLYSILICATE [J].
INAGAKI, S ;
FUKUSHIMA, Y ;
KURODA, K .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) :680-682
[10]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712