Photoelectrochemical decomposition of water utilizing monolithic tandem cells

被引：29

作者：

Kocha, SS ^{[1
]}

Montgomery, D ^{[1
]}

Peterson, MW ^{[1
]}

Turner, JA ^{[1
]}

机构：

[1] Natl Renewable Energy Lab, Golden, CO 80401 USA

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 1998年 / 52卷 / 3-4期

关键词：

decomposition; monolithic tandem cells;

D O I：

10.1016/S0927-0248(97)00245-6

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Photovoltaic tandem cells consisting of a gallium indium phosphide (GaInP2) homojunction grown epitaxially upon a gallium arsenide (GaAs) homojunction, with a GaAs tunnel-diode interconnection were utilized to photoelectrochemically decompose water in a 1 M sulfuric acid electrolyte solution. Using a sol-gel process, a platinum colloid in water was used to modify the illuminated front surface of the device to catalyze the water decomposition process. A unique feature of this device is that the hydrogen and oxygen are co-evolved from the illuminated surface. The exact mechanism of the water decomposition process is not fully understood at this time. (C) 1998 Published by Elsevier Science B.V. All rights reserved.

引用

页码：389 / 397

页数：9

共 20 条

[1] SOLAR SPECTRUM AT TYPICAL CLEAR WEATHER DAYS
BOER, KW
[J]. SOLAR ENERGY, 1977, 19 (05) : 525 - 538
[2] LIMITING AND REALIZABLE EFFICIENCIES OF SOLAR PHOTOLYSIS OF WATER
BOLTON, JR
STRICKLER, SJ
CONNOLLY, JS
[J]. NATURE, 1985, 316 (6028) : 495 - 500
[3] ULTRAFINE AND SPECIFIC CATALYSTS AFFORDING EFFICIENT HYDROGEN EVOLUTION FROM WATER UNDER VISIBLE-LIGHT ILLUMINATION
BRUGGER, PA
CUENDET, P
GRATZEL, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (11) : 2923 - 2927
[4] Damjanovic A., 1966, ELECTROCHIM ACTA, V11, P791, DOI [DOI 10.1016/0013-4686(66)87056-1, 10.1016/0013-4686, DOI 10.1016/0013-4686, 10.1016/0013-4686(66)87056-1]
[5] FAN JCC, 1981, P 16 IEEE PHOT SPEC, P21
[6] Gerischer H., 1979, Solar energy conversion. Solid-state physics aspects, P115
[7] OXYGEN ELECTROCATALYSIS ON SOME OXIDE PYROCHLORES
HOROWITZ, HS
LONGO, JM
HOROWITZ, HH
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (09) : 1851 - 1859
[8] Kocha S., 1991, J ELECTROANAL CHEM, V367, P27
[9] KOCHA S, 1991, LAB NOTES SERI
[10] KOCHA S, UNPUB

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