S-H•••S hydrogen-bond chain in thiosalicylic acid

被引:40
作者
Steiner, T [1 ]
机构
[1] Free Univ Berlin, Inst Chem Kristallog, D-14195 Berlin, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷 / 07期
关键词
D O I
10.1107/S0108270100005898
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In crystalline thiosalicylic acid (2-mercaptobenzoic acid), C7H6O2S, the carboxylic acid groups form hydrogen-bonded dimers, whereas the S-H groups form an infinite S-H ... S- H ... S-H hydrogen-bond chain, with an S ... S distance of 3.986 (3) Angstrom.
引用
收藏
页码:876 / 877
页数:2
相关论文
共 10 条
[1]   Hydrogen-bond acceptor and donor properties of divalent sulfur (Y-S-Z and R-S-H) [J].
Allen, FH ;
Bird, CM ;
Rowland, RS ;
Raithby, PR .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 :696-701
[2]  
DESIRAJU GR, 1999, WEAK HYDROGEN BOND S, P253
[3]  
Johnson C.K., 1976, Oak Ridge National Laboratory Report ORNL, P5138
[4]   Structural and IR-spectroscopic evidence of S-H•••Ph hydrogen bonding in the solid state [J].
Rozenberg, MS ;
Nishio, T ;
Steiner, T .
NEW JOURNAL OF CHEMISTRY, 1999, 23 (06) :585-586
[5]  
Sheldrick GM, 2015, ACTA CRYSTALLOGR C, V71, P3, DOI [10.1107/S2053229614024218, 10.1107/S0108767307043930]
[6]  
SHELDRICK GM, 1985, SHELXS86
[7]  
Spek A.L., 1990, ACTA CRYSTALLOGR A, VA46, pC34, DOI DOI 10.1107/S0108767390099780
[8]   Hydrogen-bond distances to halide ions in organic and organometallic crystal structures: Up-to-date database study [J].
Steiner, T .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 :456-463
[9]   REFINEMENT OF STRUCTURE OF SALICYLIC ACID [J].
SUNDARALINGAM, M ;
JENSEN, LH .
ACTA CRYSTALLOGRAPHICA, 1965, 18 :1053-+
[10]  
TAKUSAGAWA F, 1981, ACTA CRYSTALLOGR B, V37, P1591, DOI 10.1107/S0567740881006638