Volatile by-products during heat polymerization of soybean oil

被引:21
作者
Erhan, SZ [1 ]
Sheng, Q [1 ]
Hwang, HS [1 ]
机构
[1] USDA ARS, Natl Ctr Agr Utilizat Res, Peoria, IL 61604 USA
关键词
heat-bodied soybean oil; heat polymerization; soybean oil;
D O I
10.1007/s11746-003-0673-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Volatile by-products during heat polymerization of soybean oil at 330degreesC were analyzed using GC-MS and NMR. Color and viscosity changes were monitored for the heat- polymerized soybean oil and the by-products. About 90% (w/w) of the by-products were decanoic, palmitic, linoleic, oleic, and stearic acids and cis-9-tricosene, The by-products also contained small amounts of 3-eicosene, 9,17-octadecadienal, and cyclotetracosene, The weight percentage of decanoic acid increased with reaction time, whereas those of other components showed no trends.
引用
收藏
页码:177 / 180
页数:4
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