Monomeric, two-coordinate, univalent chromium(I) compounds: Steric prevention of metal-metal bond formation

被引：57

作者：

Wolf, Robert

Brynda, Marcin

Ni, Chengbao

Long, Gary J.

Power, Philip P. ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[2] Univ Missouri, Dept Chem, Rolla, MO 65409 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 19期

关键词：

D O I：

10.1021/ja0710860

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monomeric, two-coordinate, univalent, aryl chromium(I) species [(3,5-Pr-i(2)-Ar*)Cr(L)] (L = THF, PMe3) have been synthesized with use of a very bulky terphenyl ligand which prevents Cr-Cr bond formation.

引用

页码：6076 / +

页数：3

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