Crystal structures, magnetic structures and photophysics in supramolecular transition-metal oxalate compounds

被引：36

作者：

Decurtins, S

Schmalle, HW

Pellaux, R

Fischer, P

Hauser, A

机构：

[1] PSI,ETH,LAB NEUTRONENSTREUUNG,VILLIGEN,SWITZERLAND

[2] UNIV BERN,INST ANORGAN CHEM,CH-3012 BERN,SWITZERLAND

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1997年 / 305卷

关键词：

D O I：

10.1080/10587259708045060

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Polymeric two-and three-dimensional, home-and heterometallic oxalate-bridged coordination compounds offer exciting opportunities, mainly in the fields of molecular magnetism and photophysics. Given that a large variety of magnetic phenomena have been reported so far from these molecular magnets, very limited experience is gained from elastic neutron scattering experiments. Therefore, with two examples, we will address the topic of the elucidation of magnetic structures by means of the neutron scattering technique. In addition, due to the possibility of the variation of different metal ions in varying oxidation states, interesting photophysical processes can be observed within the extended three-dimensional host/guest systems.

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页码：227 / 237

页数：11

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