Efficient LEDs with a conjugated co-polymer as the emissive layer

We report on the use of a new highly luminescent conjugated polymer as an emissive layer in single and multi-layer electroluminescence devices. Poly(m-phenylenevinylene-cc-2,5-dioctyloxy-p-phenylenevinylene) [PmPV-co-DOctOPV] was prepared via a Wittig synthesis reaction, The resulting polymer has a high photoluminescence quantum efficiency in the solid state with an emission spectrum peaking at 506 nln (2.45 eV) in the green, Three different electroluminescence devices were fabricated: (i) Single layer devices containing only PmPV-co-DOctOPV; (ii) Double layer devices with PmPV-co-DOctOPV and an evaporated film of 1,3-bis(4-tert-butylphenyl-1,3,4-oxadiazoyl)phenylene [OXD-7] as an electron transport layer; (iii) Triple layer devices containing PmPV-co-DOctOPV, OXD-7 and in addition a polyvinylcarbazole [PVK] hole transport layer. All the devices utilised an ITO anode and a MgAg cathode, Electroluminescence external quantum efficiencies for these devices were found to be respectively up to 0.08%, 0.55% and 1% respectively, corresponding to luminous efficiencies of approximate to 0.5, approximate to 3 and approximate to 6 lm/W and power efficiencies of 8.5 x 10(-5), 5.9 X 10(-4) and 6.0 x 10(-4)W/W, (C) 1998 Published by Elsevier Science B,V.