Highly stable copper(I)-olefin coordination polymers capable of co-existing with water and acid

被引：61

作者：

Zhang, J

Xiong, RG ^{[1
]}

Zuo, JL

Che, CM

You, XZ

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 17期

关键词：

D O I：

10.1039/b005101m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under solvothermal conditions, the reactions of trans-3-(4-pyridyl)acrylic acid (4-HPYA) and 1,10-phenanthroline (phen), and trans-3-(3-pyridyl)acrylic acid (3-HPYA) and 2,2'-bipyridine (2,2'-bpy) with Cu(MeCN)(4)BF4 give rise to two unprecedented stable copper(I)-olefin coordination polymers, {[(phen)(4-HPYA)Cu(I)](BF4)}(n) (1) and {[(2,2'-bpy)(3-HPYA)Cu(I)](BF4). H2O}(n) (2), respectively.

引用

页码：2898 / 2900

页数：3

共 25 条

[1] Kinetics of the BpCu-catalyzed carbene transfer reaction (Bp equals dihydridobis(1-pyrazolyl)borate).: Is a 14-electron species the real catalyst for the general copper-mediated olefin cyclopropanation? [J].