Single-molecule magnets: out-of-phase ac susceptibility signals from tetranuclear vanadium(III) complexes with an S = 3 ground state

被引:77
作者
Sun, ZM
Grant, CM
Castro, SL
Hendrickson, DN
Christou, G [1 ]
机构
[1] Univ Calif San Diego, Dept Chem 0358, La Jolla, CA 92093 USA
[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
关键词
D O I
10.1039/a707266j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The salts of the tetranuclear vanadium(III) ions [V4O2(O-2-CEt)(7)(L-L)(2)](z) (L-L = bpy, z = +1; L-L = pic(-), z = -1) with a V-4 butterfly topology and a S = 3 ground state have been found to exhibit out-of-phase ac susceptibility signals, a signature of single-molecule magnets.
引用
收藏
页码:721 / 722
页数:2
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