Rational Extension of the Family of Layered, Covalent, Triazine-Based Frameworks with Regular Porosity

被引：487

作者：

Bojdys, Michael J. ^{[1
]}

Jeromenok, Jekaterina ^{[1
]}

Thomas, Arne ^{[2
]}

Antonietti, Markus ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany

[2] Tech Univ Berlin, D-10587 Berlin, Germany

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 19期

关键词：

HALOGENATION; CRYSTALLINE; POLYMERS; CARBON;

D O I：

10.1002/adma.200903436

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A layered, covalent, triazine-based framework (CTF) was synthesized via the condensation of 2,6-naphthalenedicarbonitrile under ionothermal conditions. The polytrimerization of this bi functional carbon nitrile in zinc chloride at lower temperatures yields a well-ordered, close-packed framework. At elevated temperatures an amorphous, yet porous solid is obtained, which shows remarkable thermal stability (640 degrees C) and a high surface area (2255 m(2) g(-1) and 1.51 cm(3) g(-1)).

引用

页码：2202 / +

页数：5

共 23 条

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