Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst

被引：336

作者：

Liu, Xuejun ^{[1
]}

He, Huayang ^{[1
]}

Wang, Yujun ^{[1
]}

Zhu, Shenlin ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem Engn, State Key Lab Chem Engn, Beijing 100084, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 07期

关键词：

transesterification; biodiesel; solid base catalyst; strontium oxide; ESTERS; METHANOL;

D O I：

10.1016/j.catcom.2006.10.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, transesterification of soybean oil to biodiesel using SrO as a solid base catalyst was studied. The reaction mechanism was proposed and the separate effects of reaction temperature, molar ratio of methanol to oil, mass ratio of catalyst to oil and repeated experiments were investigated. The results showed that the yield of biodiesel produced with SrO as a catalyst was in excess of 95% at temperatures below 70 degrees C within 30 min. SrO had a long catalyst lifetime and could maintain sustained activity even after being repeatedly used for 10 cycles. The results proved that transesterification of soybean oil to biodiesel using SrO as a catalyst is a commercially viable way to decrease the costs of biodiesel production. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：1107 / 1111

页数：5

共 26 条

[1] Catalytic selective oxidation of propane [J].

Buyevskaya, OV ;

Baerns, M .

CATALYSIS TODAY, 1998, 42 (03) :315-323

[2] Structure-reactivity correlations in MgAl hydrotalcite catalysts for biodiesel synthesis [J].

Cantrell, DG ;

Gillie, LJ ;

Lee, AF ;

Wilson, K .

APPLIED CATALYSIS A-GENERAL, 2005, 287 (02) :183-190

[3] Kinetic parameters affecting the alkali-catalyzed transesterification process of used olive oil [J].

Dorado, MP ;

Ballesteros, E ;

Mittelbach, M ;

López, FJ .

ENERGY & FUELS, 2004, 18 (05) :1457-1462

[4] Comparative study on lipase-catalyzed transformation of soybean oil for biodiesel production with different acyl acceptors [J].

Du, W ;

Xu, YY ;

Liu, DH ;

Zeng, J .

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2004, 30 (3-4) :125-129

[5] Selective transesterification of triolein with methanol to methyl oleate and glycerol using alumina loaded with alkali metal salt as a solid-base catalyst [J].

Ebiura, T ;

Echizen, T ;

Ishikawa, A ;

Murai, K ;

Baba, T .

APPLIED CATALYSIS A-GENERAL, 2005, 283 (1-2) :111-116

[6] VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].

FREEDMAN, B ;

PRYDE, EH ;

MOUNTS, TL .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643

[7] Interaction of oxygen with pure and SrO-doped Nd2O3 catalysts for the oxidative coupling of methane:: Study of work function changes [J].

Gayko, G ;

Wolf, D ;

Kondratenko, EV ;

Baerns, M .

JOURNAL OF CATALYSIS, 1998, 178 (02) :441-449

[8] Rapeseed oil methyl esters preparation using heterogeneous catalysts [J].

Gryglewicz, S .

BIORESOURCE TECHNOLOGY, 1999, 70 (03) :249-253

[9] Production of biodiesel fuel from triglycerides and alcohol using immobilized lipase [J].

Iso, M ;

Chen, BX ;

Eguchi, M ;

Kudo, T ;

Shrestha, S .

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2001, 16 (01) :53-58

[10] Michael addition of methyl crotonate over solid base catalysts [J].

Kabashima, H ;

Tsuji, H ;

Hattori, H .

APPLIED CATALYSIS A-GENERAL, 1997, 165 (1-2) :319-325

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