One-dimensional water and "one-dimensional acid":: Synthesis and the unique crystal structure of 1∞[H2O] ⊂ (DB18C6)(μ2-H2O)2/2]1∞[(H3O) ⊂ (DB18C6)(μ2-H2O)2/2]I3 (DB18C6=dibenzo-18-crown-6)

被引：23

作者：

Fromm, KM

Gueneau, ED

Goesmann, H

Bochet, CG

机构：

[1] Univ Geneva, Dept Inorgan Chem, CH-1211 Geneva 4, Switzerland

[2] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

[3] Univ Karlsruhe, Inst Inorgan Chem, D-7500 Karlsruhe, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2003年 / 629卷 / 04期

关键词：

one-dimensional structures; crown ethers; proton conductors;

D O I：

10.1002/zaac.200390101

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the title compound 1, the macrocylic ligand DB18C6 arranges to build two types of channels in which either only water or water and H3O+ molecules are stacked to linear polymers. The counter ions, I-3(-), also form chains and fill in the spaces left between the parallel stacks of the crown ethers. Compound 1 should therefore possess interesting conducting properties and might as well serve as model for biological water channels.

引用

收藏

页码：597 / 600

页数：4

相关论文

共 30 条

[1] Some crown ether chemistry of Ti, Zr and Hf derived from liquid clathrate media [J].

Alvanipour, A ;

Atwood, JL ;

Bott, SG ;

Junk, PC ;

Kynast, UH ;

Prinz, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (07) :1223-1228

[2] THE H3O+ CATION IN AROMATIC SOLVENTS - SYNTHESIS, STRUCTURE, AND SOLUTION BEHAVIOR OF [H3O+.18-CROWN-6][CL-H-CL] [J].

ATWOOD, JL ;

BOTT, SG ;

COLEMAN, AW ;

ROBINSON, KD ;

WHETSTONE, SB ;

MEANS, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) :8100-8101

[3] THE H3O+ CATION - MOLECULAR-STRUCTURE OF AN OXONIUM MACROCYCLIC POLYETHER COMPLEX [J].

BEHR, JP ;

DUMAS, P ;

MORAS, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (17) :4540-4543

[4] THE EVALUATION OF TRANSMISSION FACTORS AND THEIR 1ST DERIVATIVES WITH RESPECT TO CRYSTAL SHAPE-PARAMETERS [J].

BLANC, E ;

SCHWARZENBACH, D ;

FLACK, HD .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 :1035-1041

[5] Two novel lithium - 15-crown-5 complexes: An extended LiCl chain stabilized by crown ether and a dimeric complex stabilized by hydrogen bonding with water [J].

Boulatov, R ;

Du, B ;

Meyers, EA ;

Shore, SG .

INORGANIC CHEMISTRY, 1999, 38 (20) :4554-4558

[6] Chloroform as solvent for the complex formation of alkaline salts with crown ethers and cryptands [J].

Buschmann, HJ ;

Wenz, G ;

Schollmeyer, E .

INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (01) :53-56

[7] CRYSTAL STRUCTURES OF COMPLEXES BETWEEN ALKALI-METAL SALTS AND CYCLIC POLYETHERS .2. COMPLEX FORMED FROM SODIUM BROMIDE AND 2,3,11,12-DIBENZO-1,4,7,10,13,16-HEXAOXACYCLO-OCTADECA-2,11-DIENE ('DIBENZO-18-CROWN-6') [J].

BUSH, MA ;

TRUTER, MR .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (07) :1440-&

[8] Oxonium ions from aqua regia: Isolation by hydrogen bonding to crown ethers [J].

Calleja, M ;

Johnson, K ;

Belcher, WJ ;

Steed, JW .

INORGANIC CHEMISTRY, 2001, 40 (19) :4978-4985

[9] COMPLEXES OF 18-CROWN-6 WITH OXONIUM IONS DERIVED FROM TRANSITION-METAL CHLORIDES AND HYDROCHLORIC-ACID - 18-CROWN-6.H3O+.FECL4-, 18-CROWN-6.H3O+.INCL4-, (18-CROWN-6.H3O+)2.PD2CL62- [J].

CHENEVERT, R ;

CHAMBERLAND, D ;

SIMARD, M ;

BRISSE, F .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (01) :32-36

[10] A NITROGEN-GAS-STREAM CRYOSTAT FOR GENERAL X-RAY-DIFFRACTION STUDIES [J].

COSIER, J ;

GLAZER, AM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (02) :105-107