Asymmetric reductive cyclization using the intramolecular conjugate addition of enolates onto α,β-unsaturated sulfoxides

被引：19

作者：

Yoshizaki, H ^{[1
]}

Tanaka, T ^{[1
]}

Yoshii, E ^{[1
]}

Koizumi, T ^{[1
]}

Takeda, K ^{[1
]}

机构：

[1] Toyama Med & Pharmaceut Univ, Fac Pharmaceut Sci, Toyama 9300194, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 1-2期

关键词：

D O I：

10.1016/S0040-4039(97)10414-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Li(sec-Bu)(3)BH-mediated reductive cyclization of optically pure 8-((S)-p-tolylsulfinyl)(2E,7Z)-octadienoate 9 and 7-(p-tolylsulfinyl)-2,6-heptadienoate 16 afforded trans-2-((p-tolylsulfinyl)methyl)cyclohexane-l-carboxylate and trans-2-(p-tolylsulfinyl)methyl)cyclopentane-1-carboxylate, respectively, as a single isomer. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：47 / 50

页数：4

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