New process for the preparation of methyl carbonates

被引：20

作者：

Wuts, PGM ^{[1
]}

Ashford, SW ^{[1
]}

Anderson, AM ^{[1
]}

Atkins, JR ^{[1
]}

机构：

[1] Pharmacia & Upjohn Inc, Chem Proc Res & Dev, Kalamazoo, MI 49001 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 09期

关键词：

D O I：

10.1021/ol034274d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

graphic The methyl carbonate of HOBt was developed for the conversion of alcohols to carbonates. This method is superior to the use of methyl chloroformate or methyl pyrocarbonate, especially with more hindered alcohols. The reagent is a stable solid that is easily prepared on a multigram scale.

引用

页码：1483 / 1485

页数：3

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