Syntheses, properties and molecular structures of the heterobimetalorganics, of the four-valued germanium with the 2-(dimethylaminomethyl)ferrocenyl ligand FcN (η5-C5H5)Fe[η5-C5H3(CH2NMe2)-2]

被引：7

作者：

Fischer, A

Jacob, K

Edelmann, FT

机构：

[1] Univ Halle Wittenberg, Inst Anorgan Chem, D-06120 Halle An Der Saale, Germany

[2] Otto Von Guericke Univ, Inst Chem, Magdeburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2003年 / 629卷 / 06期

关键词：

heterobimetallics; ferrocene; germanium; hydrolysis; crystal structures;

D O I：

10.1002/zaac.200300007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterobimetallic lithiumorganyl [2-(dimethylamino-methyl)ferrocenyl] lithium, FcNLi, reacts with germanium(IV) chloride, GeCl4, under the formation of heterobimetallic germanium(IV) organyls (FcN)(n)GeCl4-n (n = 2 (1), 3 (2)). The heterobimetallic organogermanol (FcN)(3)GeOH (3) is formed at hydrolysis of 2. A detailed characterization of the defined compounds 1-3 was carried out by single crystal X-ray analyses, NMR- and mass-spectrometry.

引用

页码：963 / 967

页数：5

共 22 条

[1] Synthesis and characterization of new germylferrocenyl, germylferrocenophane and polymeric germyleneferrocenylene systems [J].