Direct methanol alkaline fuel cells with catalysed anion exchange membrane electrodes

被引:58
作者
Yu, EH [1 ]
Scott, K [1 ]
机构
[1] Univ Newcastle Upon Tyne, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
基金
英国工程与自然科学研究理事会;
关键词
alkaline; anion exchange membrane; catalysed membrane; chemical deposition of platinum; methanol;
D O I
10.1007/s10800-004-4061-2
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Membrane electrodes prepared by chemical deposition of platinum directly onto the anion exchange membrane electrolyte were tested in direct methanol alkaline fuel cells. Data on the cell voltage against current density performance and anode potentials are reported. The relatively low fuel cell performance was probably due to the low active surface area of Pt deposits on the membrane comparing to other membrane electrode assembly (MEA) fabrication methods. However, the catalysed membrane electrode showed good performance for oxygen reduction. A reduction in cell internal resistance was also obtained for the catalysed membrane electrode. By combining the catalysed membrane electrodes with a catalysed mesh, maximum current density of 98 mA cm(-2) and peak power density of 18 mW cm(-2) stop were achieved.
引用
收藏
页码:91 / 96
页数:6
相关论文
共 18 条
[1]  
ALLEN RG, 2004, THESIS U NEWCASTLE U
[2]   A novel high power density borohydride-air cell [J].
Amendola, SC ;
Onnerud, P ;
Kelly, MT ;
Petillo, PJ ;
Sharp-Goldman, SL ;
Binder, M .
JOURNAL OF POWER SOURCES, 1999, 84 (01) :130-133
[3]   Alkaline anion-exchange radiation-grafted membranes for possible electrochemical application in fuel cells [J].
Danks, TN ;
Slade, RCT ;
Varcoe, JR .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (04) :712-721
[4]   Comparison of PVDF- and FEP-based radiation-grafted alkaline anion-exchange membranes for use in low temperature portable DMFCs [J].
Danks, TN ;
Slade, RCT ;
Varcoe, JR .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) :3371-3373
[5]  
Delime F, 1998, J APPL ELECTROCHEM, V28, P27
[6]  
JASINSKI R, 1965, ELECTROCHEM TECHNOL, V3, P40
[7]  
KITA H, 1992, ELECTROCHEMISTRY TRA, P619
[8]   A fuel cell development for using borohydrides as the fuel [J].
Li, ZP ;
Liu, BH ;
Arai, K ;
Suda, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (07) :A868-A872
[9]   PREPARATION OF NEW SOLID POLYMER ELECTROLYTE COMPOSITES FOR WATER ELECTROLYSIS [J].
MILLET, P ;
DURAND, R ;
PINER, M .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1990, 15 (04) :245-253
[10]   NEW SOLID POLYMER ELECTROLYTE COMPOSITES FOR WATER ELECTROLYSIS [J].
MILLET, P ;
PINERI, M ;
DURAND, R .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1989, 19 (02) :162-166