Relative M-X bond dissociation energies in 16-, 17- and 18-electron organotransition-metal complexes (X=halide, H)

被引：32

作者：

Tilset, M

Hamon, JR

Hamon, P

机构：

[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway

[2] Univ Rennes 1, UMR CNRS 6509, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 07期

关键词：

D O I：

10.1039/a800742j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Fe-halide bonds in Cp*Fe(dppe)X (X = F, Cl, Br, I) complexes are weakened as a consequence of one and two-electron oxidations; the bond weakening decreases in the order F < < Cl < Br < I and is much less pronounced for F than the other halides, indicating a pronounced effect of apparent fluoride-to-metal backbonding as a consequence of the removal of electrons.

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页码：765 / 766

页数：2

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