Asymmetric acylation of meso-diols with benzoyl halide in the presence of a chiral diamine

被引：79

作者：

Oriyama, T ^{[1
]}

Imai, K ^{[1
]}

Hosoya, T ^{[1
]}

Sano, T ^{[1
]}

机构：

[1] Ibaraki Univ, Fac Sci, Mito, Ibaraki 310, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 5-6期

关键词：

D O I：

10.1016/S0040-4039(97)10558-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nonenzymatic desymmetrization of cis-1,2-cyclohexanediol by the asymmetric acylation with achiral benzoyl chloride in the presence of a chiral diamine derived from (S)-proline took place to give monobenzoate in high optical yield. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：397 / 400

页数：4

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