The preparation of supported NiO and Co3O4 nanoparticles by the nitric oxide controlled thermal decomposition of nitrates

被引:213
作者
Sietsma, Jelle R. A.
Meeldijk, Johannes D.
den Breejen, Johan P.
Versluijs-Helder, Marjan
van Dillen, A. Jos
de Jongh, Petra E.
de Jong, Krijn P.
机构
[1] Univ Utrecht, NL-3584 CA Utrecht, Netherlands
[2] Univ Utrecht, Electron Microscopy Utrecht EMU, NL-3584 CH Utrecht, Netherlands
关键词
cobalt; nanostructures; nickel; nitric oxide; supported catalysts;
D O I
10.1002/anie.200700608
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A need for NO: Moderating the thermal decomposition of supported nitrates with NO (see picture, center) prevents precursor mobility and is a versatile method for the preparation of small NiO (left; compared to the product of the conventional procedure, right) and Co3O4 particles. These materials can be used as heterogeneous catalysts and show good activity in the Fischer-Tropsch synthesis. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:4547 / 4549
页数:3
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