Isolation of electronic from geometric contributions to Bergman cyclization of metalloenediynes

被引：23

作者：

Bhattacharyya, S ^{[1
]}

Clark, AE ^{[1
]}

Pink, M ^{[1
]}

Zaleski, JM ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 10期

关键词：

D O I：

10.1039/b301690k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conformationally constrained ethylene-diamine metalloenediyne compounds exhibit alkyne termini separations that are constant and independent of metal center geometry. Ancillary chloride ligand electron donation into the Bergman cyclization reaction coordinate, however, dramatically influences the observed temperatures.

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页码：1156 / 1157

页数：2

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