Diels-Alder reactivity of a ketovinylphosphonate with cyclopentadiene and furan.

被引：27

作者：

McClure, CK ^{[1
]}

Hansen, KB ^{[1
]}

机构：

[1] UNIV DELAWARE, DEPT CHEM & BIOCHEM, NEWARK, DE 19716 USA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 13期

关键词：

D O I：

10.1016/0040-4039(96)00235-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder reactions between diethyl ketovinylphosphonate 5 and cyclopentadiene or furan were performed with and without Lewis acid assistance. The acetyl group directed endo in all cases, with ratios varying from 1.4:1 - 6.7:1 (acetyl endo).

引用

页码：2149 / 2152

页数：4

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