Radioanalytical determination of biogenic volatile iodine emitted from aqueous environmental samples

被引:8
作者
Amachi, S
Muramatsu, Y
Kamagata, Y
机构
[1] Agcy Ind Sci & Technol, Natl Inst Biosci & Human Technol, Tsukuba, Ibaraki 3058566, Japan
[2] Natl Inst Radiol Sci, Chiba 2638555, Japan
关键词
D O I
10.1023/A:1006786826998
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A reliable method using I-125 tracer for direct determination of volatile iodine formed in aqueous environmental samples was established Soil solution, seawater and bacterial cell suspension were selected as model samples, and incubated with I-125(-). Volatile inorganic and organic iodine species produced during incubation were collected in silver wool and activated charcoal traps, separately the efficiency of the traps, the storage conditions of I-125(-) stock solution and the procedures to expel the dissolved volatile iodine from the sample solutions were examined. Formation of biological volatile iodine was observed in all samples, and the dominant iodine species was found to be organic iodine. The advantages of this method are its simplicity, low cost and low detection limit.
引用
收藏
页码:337 / 341
页数:5
相关论文
共 22 条
[1]   Short-lived alkyl iodides and bromides at Mace Head, Ireland: Links to biogenic sources and halogen oxide production [J].
Carpenter, LJ ;
Sturges, WT ;
Penkett, SA ;
Liss, PS ;
Alicke, B ;
Hebestreit, K ;
Platt, U .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1999, 104 (D1) :1679-1689
[2]   IODINE - ITS POSSIBLE ROLE IN TROPOSPHERIC PHOTOCHEMISTRY [J].
CHAMEIDES, WL ;
DAVIS, DD .
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1980, 85 (NC12) :7383-7398
[3]   THE GEOCHEMISTRY OF IODINE - A REVIEW [J].
FUGE, R ;
JOHNSON, CC .
ENVIRONMENTAL GEOCHEMISTRY AND HEALTH, 1986, 8 (02) :31-54
[4]   SEASONAL-VARIATIONS OF BIOGENIC AND ANTHROPOGENIC HALOCARBONS IN SEAWATER FROM A COASTAL SITE [J].
KLICK, S .
LIMNOLOGY AND OCEANOGRAPHY, 1992, 37 (07) :1579-1585
[5]   BIOGENIC VOLATILE IODATED HYDROCARBONS IN THE OCEAN [J].
KLICK, S ;
ABRAHAMSSON, K .
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1992, 97 (C8) :12683-12687
[6]   FLUX OF GASES ACROSS AIR-SEA INTERFACE [J].
LISS, PS ;
SLATER, PG .
NATURE, 1974, 247 (5438) :181-184
[7]   NATURAL HALOCARBONS IN AIR AND IN SEA [J].
LOVELOCK, JE .
NATURE, 1975, 256 (5514) :193-194
[8]   THE POSSIBLE INVOLVEMENT OF METHYLCOBALAMIN IN THE PRODUCTION OF METHYL-IODIDE IN THE MARINE-ENVIRONMENT [J].
MANLEY, SL .
MARINE CHEMISTRY, 1994, 46 (04) :361-369
[9]   LABORATORY PRODUCTION OF BROMOFORM, METHYLENE BROMIDE, AND METHYL-IODIDE BY MACROALGAE AND DISTRIBUTION IN NEARSHORE SOUTHERN CALIFORNIA WATERS [J].
MANLEY, SL ;
GOODWIN, K ;
NORTH, WJ .
LIMNOLOGY AND OCEANOGRAPHY, 1992, 37 (08) :1652-1659
[10]   Methyl iodide production from marine phytoplankton cultures [J].
Manley, SL ;
delaCuesta, JL .
LIMNOLOGY AND OCEANOGRAPHY, 1997, 42 (01) :142-147