Poly(vinyl acetate) and poly(vinyl propionate) star polymers via reversible addition fragmentation chain transfer (RAFT) polymerization

被引：69

作者：

Boschmann, D ^{[1
]}

Vana, P ^{[1
]}

机构：

[1] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany

来源：

POLYMER BULLETIN | 2005年 / 53卷 / 04期

关键词：

D O I：

10.1007/s00289-005-0338-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(vinyl acetate) and poly( vinyl propionate) star polymers with four arms were produced via reversible addition fragmentation chain transfer (RAFT) polymerization, employing a tetra-functional xanthate as the RAFT agent, in which the stabilizing groups are linked to the core. These novel star-like RAFT agents induced living/controlled behavior in both the vinyl acetate polymerization at 60 degreesC and in the vinyl propionate polymerization at 90 degreesC, respectively, leading to star polymers with minimum polydispersities of 1.2 and maximum apparent number average molecular weights of about 50,000 g . mol(-1). The microstructure of the star polymers was confirmed by electrospray ionization mass spectrometry.

引用

页码：231 / 242

页数：12

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