Induced adsorption of phosphate (H2PO4-) species by Zn adatoms on platinum

被引：15

作者：

Horanyi, G

Aramata, A

机构：

[1] Hungarian Acad Sci, Cent Res Inst Chem, H-1525 Budapest, Hungary

[2] Hokkaido Univ, Ctr Catalysis Res, Sapporo, Hokkaido 6, Japan

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 437卷 / 1-2期

关键词：

Zn; Upd; induced anion adsorption; phosphate; radiotracer technique;

D O I：

10.1016/S0022-0728(97)00392-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The specific adsorption of H2PO4- ions accompanying the upd of Zn2+ ions on platinum electrodes has been studied by a radiotracer technique using P-32 labelled phosphate species in the presence of a great excess of ClO4- ions. It has been found that the specific adsorption of species induced by Zn adatoms depends on pH and at a given potential on the concentration of Zn2+ ions. (C) 1997 Elsevier Science S.A.

引用

页码：259 / 262

页数：4

共 7 条

[1]

HORANYI G, 1974, J ELECTROANAL CHEM, V55, P287, DOI 10.1016/0368-1874(74)87133-9

[2] RADIOTRACER STUDY OF THE ADSORPTION OF CL- AND HSO4- IONS ON A POROUS GOLD ELECTRODE AND ON UNDERPOTENTIAL DEPOSITED METALS ON GOLD [J].