Photocatalytic behaviors of transition metal ion doped TiO2 powder synthesized by mechanical alloying

被引:41
作者
Woo, S. H.
Kim, W. W.
Kim, S. J.
Rhee, C. K. [1 ]
机构
[1] Korea Atom Energy Res Inst, Nucl Nanomat Dev Lab, Taejon 305600, South Korea
[2] Sejong Univ, Dept Nano Sci & Technol, Seoul 143747, South Korea
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2007年 / 449卷
关键词
TiO2; powder; transition metal ion; mechanical alloying; photocatalyst;
D O I
10.1016/j.msea.2006.01.165
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Transition metal ion of Ni2+ doped TiO2 nanostructured powders were synthesized by mechanical alloying to shift the adsorption threshold into the visible light region. The X-ray patterns for samples showed three phases of TiO2 such as rutile, anatase and brookite. The 8 wt.% Ni-doped TiO2 powders consisted of spherical primary particles with a size of about 50 nm and secondary particles about 100-300 nm. The transition metal ion of Ni2+ doped TiO2 powders showed excellent photo-oxidative ability in 4-chlorophenol degradation. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1151 / 1154
页数:4
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