Side-chain migration reactions and ring B aromatization in labdanes:: scope and limitations.: Synthesis of isofregenedane type tetrahydronaphthalenic diterpenes

被引：23

作者：

Marcos, IS

Basabe, P

Laderas, M

Díez, D

Jorge, A

Rodilla, JM

Moro, RF

Lithgow, AM

Barata, IG

Urones, JG

机构：

[1] Univ Salamanca, Fac Ciencias Quim, Dept Quim Organ, E-37008 Salamanca, Spain

[2] Univ Beira Interior, Dept Quim, P-6200 Covilha, Portugal

来源：

TETRAHEDRON | 2003年 / 59卷 / 13期

关键词：

isofregenedane; labdanes; aromatization;

D O I：

10.1016/S0040-4020(03)00247-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of bicyclic diterpenes with an allylic oxygenated function or an equivalent functionality on ring B in the presence of I-2/benzene afforded a simple and rapid synthesis of tetrahydronaphthalenic diterpenes of the isofregenedane class. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：2333 / 2343

页数：11

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