Multiple internal reflection FT-IR spectroscopy (MIRFTIRS) study of the electrochemical synthesis and the redox process of poly(1,5-diaminonaphthalene)

被引：46

作者：

Pham, MC ^{[1
]}

Oulahyane, M ^{[1
]}

Mostefai, M ^{[1
]}

Chehimi, MM ^{[1
]}

机构：

[1] Univ Paris 07, Inst Topol & Dynam Syst, CNRS, URA 34, F-75005 Paris, France

来源：

SYNTHETIC METALS | 1998年 / 93卷 / 02期

关键词：

FT-IR spectroscopy; poly(1,5-diaminonaphthalene); redox processes;

D O I：

10.1016/S0379-6779(97)03946-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrooxidation of 1,5-diaminonaphthalene (1,5-DAN) in acidic aqueous, methanol and organic media leads to polymer film on glassy carbon and Pt electrodes. The in situ infrared study during film growth and X-ray photoelectron spectroscopy (XPS) analysis indicate that the polymer structure consists of amine (-NH-C) and imine (-N=C) units, bearing free -NH2 groups in the chain. The polymer structure was confirmed by a multiple internal reflection FT-IR spectroscopy (MIRFTIRS) study of the film redox process and by the ability of poly(1,5-DAN) film to chelate copper ions. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：89 / 96

页数：8

共 19 条

[1] ELECTROPOLYMERIZATION OF 1,5-DIAMINONAPHTHALENE IN ACETONITRILE AND IN AQUEOUS-SOLUTION [J].