Magnetic properties of the filled skutterudite-type structure compounds GdRu4P12 and TbRu4P12 synthesized under high pressure

被引:76
作者
Sekine, C
Uchiumi, T
Shirotani, I
Matsuhira, K
Sakakibara, T
Goto, T
Yagi, T
机构
[1] Muroran Inst Technol, Dept Elect & Elect Engn, Muroran, Hokkaido 0508585, Japan
[2] Hokkaido Univ, Grad Sch Sci, Div Phys, Sapporo, Hokkaido 0600810, Japan
[3] Univ Tokyo, Inst Solid State Phys, Minato Ku, Tokyo 1068666, Japan
来源
PHYSICAL REVIEW B | 2000年 / 62卷 / 17期
关键词
D O I
10.1103/PhysRevB.62.11581
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have succeeded in synthesizing Filled skutterudite-type structure compounds GdRu4P12 and TbRu4P12 under high pressure. The magnetic properties of GdRu4P12 and TbRu4P12 have been studied by means of electrical resistivity, magnetic susceptibility, and magnetization measurements. Magnetic experiments suggest that the Gd and Tb ions in the compounds have trivalent state. The compound GdRu4P12 displays features that suggest the occurrence of antiferromagnetic ordering below T-N=22 K. In TbRu4P12, thermal variation of magnetic susceptibility indicates the existence of two successive magnetic transitions (T-N=20 K and T-1 = 10 K). Magnetization up to 18 T exhibits two-step metamagnetic transitions below T1 for TbRu4P12.
引用
收藏
页码:11581 / 11584
页数:4
相关论文
共 20 条
[1]   TERNARY ARSENIDES WITH LAFE4P12-TYPE STRUCTURE [J].
BRAUN, DJ ;
JEITSCHKO, W .
JOURNAL OF SOLID STATE CHEMISTRY, 1980, 32 (03) :357-363
[2]   PREPARATION AND STRUCTURAL INVESTIGATIONS OF ANTI-MONIDES WITH THE LAFE4P12 STRUCTURE [J].
BRAUN, DJ ;
JEITSCHKO, W .
JOURNAL OF THE LESS-COMMON METALS, 1980, 72 (01) :147-156
[3]   Low-temperature transport properties of the filled skutterudites CeFe4-xCoxSb12 [J].
Chen, BX ;
Xu, JH ;
Uher, C ;
Morelli, DT ;
Meisner, GP ;
Fleurial, JP ;
Caillat, T ;
Borshchevsky, A .
PHYSICAL REVIEW B, 1997, 55 (03) :1476-1480
[4]   Magnetic properties of alkaline earth and lanthanoid iron antimonides AFe(4)Sb(12) (A=Ca,Sr,Ba, La-Nd,Sm,Eu) with the LaFe4P12 structure [J].
Danebrock, ME ;
Evers, CBH ;
Jeitschko, W .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (04) :381-387
[5]   Intermediate valence in the filled skutterudite compound YbFe4Sb12 [J].
Dilley, NR ;
Freeman, EJ ;
Bauer, ED ;
Maple, MB .
PHYSICAL REVIEW B, 1998, 58 (10) :6287-6290
[6]  
HARIMA H, IN PRESS PROG THEO S
[7]   LAFE4P12 WITH FILLED COAS3-TYPE STRUCTURE AND ISOTYPIC LANTHANOID-TRANSITION METAL POLYPHOSPHIDES [J].
JEITSCHKO, W ;
BRAUN, D .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (NOV) :3401-3406
[8]   The antimony-rich parts of the ternary systems calcium, strontium, barium and cerium with iron and antimony;: structure refinements of the LaFe4Sb12-type compounds SrFe4Sb12 and CeFe4Sb12;: the new compounds CaOs4Sb12 and YbOs4Sb12 [J].
Kaiser, JW ;
Jeitschko, W .
JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 291 (1-2) :66-72
[9]   UFE4P12 AND CEFE4P12 - NONMETALLIC ISOTYPES OF SUPERCONDUCTING LAFE4P12 [J].
MEISNER, GP ;
TORIKACHVILI, MS ;
YANG, KN ;
MAPLE, MB ;
GUERTIN, RP .
JOURNAL OF APPLIED PHYSICS, 1985, 57 (08) :3073-3075
[10]   LOW-TEMPERATURE PROPERTIES OF THE FILLED SKUTTERUDITE CEFE4SB12 [J].
MORELLI, DT ;
MEISNER, GP .
JOURNAL OF APPLIED PHYSICS, 1995, 77 (08) :3777-3781