Application of phosphine-oxazoline ligands in Ir-catalyzed asymmetric hydrogenation of acyclic aromatic N-arylimines

被引：95

作者：

Trifonova, A ^{[1
]}

Diesen, JS ^{[1
]}

Chapman, CJ ^{[1
]}

Andersson, PG ^{[1
]}

机构：

[1] Uppsala Univ, Dept Chem, SE-75124 Uppsala, Sweden

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 21期

关键词：

D O I：

10.1021/ol048399+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(GRAPHICS) A new class of chiral phosphine-oxazoline ligands have been developed. Chiral Ir complexes prepared from these ligands induced high enantioselectivities (66-90% ee) when applied to the asymmetric hydrogenation of acyclic aromatic N-arylimines.

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页码：3825 / 3827

页数：3

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