Ionic liquids as reagents and solvents in conjunction with microwave heating: rapid synthesis of alkyl halides from alcohols and nitriles from aryl halides

被引：74

作者：

Leadbeater, NE

Torenius, HM

Tye, H

机构：

[1] Kings Coll London, Dept Chem, London WC2R 2LS, England

[2] Evotec OAI, Abingdon OX14 4SD, Oxon, England

来源：

TETRAHEDRON | 2003年 / 59卷 / 13期

关键词：

ionic liquids; alkyl halides; nitriles;

D O I：

10.1016/S0040-4020(03)00214-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We show that using ionic liquids as reagents in conjunction with microwave heating it is possible to prepare primary alkyl halides from the corresponding alcohols rapidly. Using ionic liquids as solvents in conjunction with microwave heating it is possible to prepare aryl nitriles from the corresponding aryl bromides or iodides. The scope and limitations of using microwave-promotion as a tool in these reactions is discussed. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：2253 / 2258

页数：6

共 43 条

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