6,6′-bis-(5,6-diethyl-[1,2,4]triazin-3-yl)-2,2′-bipyridyl the first example of a new class of quadridentate hetercyclic extraction reagents for the separation of americium(III) and europium(III)

被引：135

作者：

Drew, MGB

Foreman, MRSJ

Hill, C

Hudson, MJ

Madic, C

机构：

[1] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

[2] CEA, DRCP, SCPS, LCSE,Commissariat Energie Atom, F-30207 Bagnols Sur Ceze, France

[3] CEA Saclay, Commissariat Energie Atom, DEN, DDIN, F-9119 Gif Sur Yvette, France

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

americium(III); europium(III); separation; quadridentate heterocycles;

D O I：

10.1016/j.inoche.2004.12.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the first example of a new class of tetradentate reagents for the efficient separation of americium(Ill) and europium(111) is reported together with the structure of the complex formed with europium(III), (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：239 / 241

页数：3

共 13 条

[1]

Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31

[2] NOVEL TETRA-DENTATE AND HEXA-DENTATE LIGANDS FROM 6,6'-DICYANO-2,2'-BIPYRIDINE [J].