Cyclization reactions of dianions in organic synthesis

被引：153

作者：

Langer, P ^{[1
]}

Freiberg, W ^{[1
]}

机构：

[1] Ernst Moritz Arndt Univ Greifswald, Inst Chem & Biochem, D-17487 Greifswald, Germany

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 09期

关键词：

D O I：

10.1021/cr010203l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dianions are reactive organic intermediates containing two negative charges. This review outlines the cyclization reactions of dianions. Selected examples of cyclization reactions that follow either a 1:1 stoichiometry of dianion and electrophile or an oxidative pathway are discussed. The cyclization reactions considered include, at least one, formation of a carbon-carbon bond. For comparison purposes, a few transformations that involve the formation of a carbon-silicon are also considered.

引用

页码：4125 / 4149

页数：25

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