The first sandwich silver cluster of a trinuclear cyclic gold(I) complex

被引:71
作者
Burini, A
Fackler, JP
Galassi, R
Pietroni, BR
Staples, RJ
机构
[1] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy
[2] Texas A&M Univ, Mol Struct & Bonding Lab, College Stn, TX 77843 USA
[3] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[4] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA
关键词
D O I
10.1039/a706795j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new type of metal sandwich structure [Ag{[Au(mu-N-3,C-2-bzim)](3)}(2)]BF4 . CH2Cl2 1, is formed by reacting the neutral, triangular cluster [Au(mu-N-3,C-2-bzim)](3) with Ag+; these units stack with two short intermolecular Au ... Au distances of ca. 3.2 Angstrom.
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页码:95 / 96
页数:2
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